Silica Nanoparticle Separation from Water by Aggregation with AlCl3
نویسندگان
چکیده
Nanotechnology that is vigorously developed nowadays will inevitably let nanoparticles into water resources. Since these ultrasmall particles may have potential risks for human and animals, it is reasonable to consider urgently how to manage these polluted waters. The direct separation would be difficult due to their small size and high surface area, so AlCl3 is added to modify surface physicochemical properities of nanosilica in order to produce aggregates. Early stages and long time equilibrium of nanosilica aggregation are explored. In the kinetics study (early stage), the influences of particle concentrations and particle sizes are studied and compared. The aggregation results at long time equilibrium are further investigated, which shows the charge neutralization effect could be overcome by other mechanisms. More than 99% of the turbidity can be removed from aggregation of nanosilica by AlCl3 after sedimentation.
منابع مشابه
Synthesis of Silica-coated Iron Oxide Nanoparticles: Preventing Aggregation Without Using Additives or Seed Pretreatment
The Stober process is frequently used to prepare silica-coated iron oxide nanoparticles. This is usually achieved by seeding a reaction mixture consisting of water, ethanol and a catalyst with iron oxide particles and adding a silica precursor. The hydrolysis and condensation of precursor monomers results in the deposition of a silica layer on iron oxide particles. However, this process is acco...
متن کاملSynthesis of Silica-coated Iron Oxide Nanoparticles: Preventing Aggregation Without Using Additives or Seed Pretreatment
The Stober process is frequently used to prepare silica-coated iron oxide nanoparticles. This is usually achieved by seeding a reaction mixture consisting of water, ethanol and a catalyst with iron oxide particles and adding a silica precursor. The hydrolysis and condensation of precursor monomers results in the deposition of a silica layer on iron oxide particles. However, this process is acco...
متن کاملSilver Nanoparticles Adsorbent For Separation And Pre-Concentration Of Iron From Water Samples
In this work, an simple and fast method based solid phase extraction for preconcentration and separation of trace amount of Fe(III) ions from water samples prior to its determination by flame atomic absorption spectrometry (FAAS) was developed. The silver nanoparticles coated silica gel was modified by morin and then it was used as a adsorbent. The silver nanoparticle coated silica gel was prep...
متن کاملSeparation of Curcumin from Curcuma longa L. and its Conjugation with Silica Nanoparticles for Anti-cancer Activities
Curcumin is the natural bio-active component of turmeric (Curcuma longa L.) with known therapeutic properties; nevertheless, its biological applications are limited due to its poor bioavailability. To overcome this limitation, curcumin was conjugated with silica nanoparticles. Curcumin was separated from turmeric by microwave-assisted extraction and silica nanoparticles were developed from rice...
متن کاملSurface modification of silica nanoparticles to reduce aggregation and nonspecific binding.
In this article, a systematic study of the design and development of surface-modification schemes for silica nanoparticles is presented. The nanoparticle surface design involves an optimum balance of the use of inert and active surface functional groups to achieve minimal nanoparticle aggregation and reduce nanoparticle nonspecific binding. Silica nanoparticles were prepared in a water-in-oil m...
متن کامل